Add time:08/17/2019         Source:sciencedirect.com

In this study, a novel phthalonitrile, ethyl 7-(3,4-dicyanophenoxy)coumarin-3-carboxylate (1), was prepared and characterized. The metallophthalocyanines (3–6) were prepared by cyclotetramerization of 1 with the corresponding metal salts {Zn(OAc)2·2H2O, Co(OAc)2·4H2O, Cu(OAc)2, Ni(OAc)2·4H2O} in 2-chloronaphthalene. Reaction of 3 with aqueous hydrochloric acid gave the coumarino-zincphthalocyanine (3a) carrying carboxyl groups at the 3-position of all the coumarin moieties. Treatment of compound 3a with aqueous NaOH./AgNO3 or aqueous NaOH in N,N-dimethylformamide (DMF) gave the expected silver (3c) or sodium (3d) salts, respectively. The four carboxylic groups in coumarino-zincphthalocyanine (3a) and the four carboxylate groups in 3d make the compounds have good solubility in water. Heating of the acyl chloride derivative of 3 with morpholine in DMF yielded the corresponding 3-carboxymorpholinamide (3b). The newly prepared compounds, phthalonitrile and metallophthalocyanines, have been characterized by FT-IR, UV–Vis, MALDI-TOF and 1H NMR spectroscopies.

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