Add time:08/21/2019         Source:sciencedirect.com

The electronic structures of aluminium, gallium and indium tris-acetylacetonates were investigated by methods of photoelectron, absorption electronic spectroscopy and quantum chemistry. The experimental and theoretical ionization energies and electron transition energies were determined; the nature of correspondent ground, ionized and excited states was studied. The main regularities of electronic spectra changes during central atom substitution were established. The communication between geometry and some energetical characteristics of present compounds in ground, excited and ionized states were studied.

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