Copper(I) carboxylate catalyzed C–N coupling of 2-amino pyrimidines with aryl halides to selectively generate secondary and tertiary amines-Science-Chemical Encyclopedia-lookchem

Copper(I) carboxylate catalyzed C–N coupling of 2-amino pyrimidines with aryl halides to selectively generate secondary and tertiary amines
Add time:08/17/2019 Source:sciencedirect.com

(2-Chlorobenzoyloxy)copper(I) exhibited high activity towards the challenging amination of 2-amino pyrimidines with aryl halides. Herein, secondary and tertiary amines were selectively produced by using potassium phosphate and sodium-t-butoxide. Potassium phosphate favored the formation of secondary amines, whereas tertiary amines were favored when sodium-t-butoxide was used.

We also recommend Trading Suppliers and Manufacturers of 2-(2-bromophenylamino)pyrimidine (cas 127813-30-3). Pls Click Website Link as below: cas 127813-30-3 suppliers

Prev:[λ‑Carrageenan‑calcium phosphate] and [sodium alginate‑calcium phosphate] modified with dimethyl diallyl ammonium chloride and diallylamin co-polymer as efficient adsorbents of anionic dyes
Next: Research paperDesign and synthesis of novel pyrazolo[1,5-a]pyrimidine derivatives bearing nitrogen mustard moiety and evaluation of their antitumor activity in vitro and in vivo)

Click to view details

Encyclopedia