Peculiar Sharpless kinetic resolution of 2-furylmethanol and its application to the synthesis of (+)-Asperlin-Science-Chemical Encyclopedia-lookchem

Peculiar Sharpless kinetic resolution of 2-furylmethanol (cas 93793-62-5) and its application to the synthesis of (+)-Asperlin
Add time:07/13/2019 Source:sciencedirect.com

A peculiar kinetic resolution of E-1-(2-furyl)-2-buten-1-ol (1), which produced two oxidation products, pyranone (2) and epoxyalcohol (3), was developed by using the modified Sharpless reagents. A short synthesis of (+)-Asperlin was achieved starting from the optically active resolution products.

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