Add time:08/22/2019         Source:sciencedirect.com

Excess molar enthalpies, HEm, have been measured using a flow microcalorimeter at 298.15 K and at atmospheric pressure for the eight mixtures containing 1,2-EPOXYBUTANE (cas 106-88-7) with ethyl acetate, ethyl propanoate, ethyl butyrate, ethyl pentanoate, ethyl hexanoate, ethyl heptanoate, ethyl octanoate and ethyl decanoate. Excess heats of mixing, HEm, are positive for all the mixtures and increase with the chain length of the alkanoate, with the exception of ethyl acetate whose HEm values were between those of ethyl pentanoate and ethyl hexanoate. Results have been correlated in terms of the Redlich–Kister equation and qualitatively discussed in terms of molecular interactions.

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