Add time:08/18/2019 Source:sciencedirect.com
Infrared and Raman spectra were obtained for 1,3-dichlorobutane and 1,3-dibromobutane. Five CBr stretch bands were observed for dibromobutane, but only three CCl stretch bands were observed for dichlorobutane. Normal coordinate calculations were made for several conformers of both compounds, and it has been concluded that 1,3-dibromobutane exists as four conformers (PHSHH, PCSHH, and PCSCH), but that 1,3-dichlorobutane exists as only two conformers (PHSHH and PCSHH).
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