Add time:08/18/2019         Source:sciencedirect.com

Oil derived from fast pyrolysis of biomass (or bio-oil) is a candidate renewable feedstock for producing hydrogen (H2). In this work, the steam reforming of model oxygenates present in the bio-oil aqueous fraction was studied in a fixed-bed reactor. Using Ni/Al2O3 catalyst, the reactions with 2-butanone, 1-methoxy-2-propanol, ethyl acetate and butyraldehyde were studied. To study the efficacy of the chosen catalyst for H2 production, experiments were performed in the 623–773 K range using varying steam/carbon ratios in feed (15–25 mol/mol). The conversion of the various feeds was of the order: butyraldehyde > ethyl acetate > 1-methoxy-2-propanol > 2-butanone. The catalyst was characterized using SEM, XRD, TPR/TPD and TGA methods. It showed high stability for 7 h of time-on-stream.

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