Add time:08/18/2019         Source:sciencedirect.com

Reactions of cyclic enaminones, derived from cyclic five- and six-membered 1,3-diones, and dimethyl acetylenedicarboxylate (DMAD) under microwave irradiation produced a mixture of two products: ring-expansion products as a result of a [2+2] cycloaddition and Michael adducts. Reaction between 4-(dimethylamino)-2H-chromen-2-one and DMAD leads to three products: 2-(4-(dimethylamino)-2-oxo-2H-chromen-3-yl)maleate as a Michael adduct, dimethyl 1-(dimethylamino)naphthalene-2,3-dicarboxylate as the product of the [2+2] cycloaddition followed by 6π disrotatory electrocyclization and elimination of CO2 and 4-(dimethylamino)naphthalene-1,2-dicarboxylate as the product of the [4+2] cycloaddition followed by elimination of CO2.

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