Add time:08/18/2019 Source:sciencedirect.com
Complex formation between Ni(II), Co(II) and Mn(II) and 3-(2-furyl)-2-mercaptopropenoic and 3-(2-furyl)-2-mercaptopropanoic acids has been studied using glass electrode potentiometry. Ligand-metal ion mixtures in 10% (v/v) ethanol-water containing 0.1 mol dm–3KNO3 were titrated with potassium hydroxide. The e.m.f. data obtained have been analyzed using the linearization method, and initial estimates of protonation constants for the ligands and complex formation constants have been refined with the MINIQUAD program.
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