Add time:08/24/2019 Source:sciencedirect.com
4-Methylmorpholine (cas 109-02-4) has been fluorinated with cobalt(iii) fluoride to give ten highly fluorinated morpholines and one minor breakdown product. Mass spectrometry and NMR spectroscopy (1H and 19F) were utilised extensively in the assignment of product structures. A cation-radical mechanism is proposed.
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