Add time:08/23/2019 Source:sciencedirect.com
The surface-enhanced Raman scattering (SERS) of 1-Butanethiol (cas 109-79-5) was investigated in a silver sol. The molecule was found to be chemisorbed dissociatively on the silver surface by rupture of its SH bond. It is concluded that conformers of 1-butanethiol adsorbed selectively on the silver surface, the trans conformer around the C (1)C (2) axes being more likely adsorbed when the bulk concentration of the molecule is enough for the full monolayer coverage. The vibrational assignment of the molecule in liquid phase has also been refined by using the SERS data.
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