Add time:08/27/2019         Source:sciencedirect.com

The rate coefficient of the reaction of Dimethoxymethane (cas 109-87-5) with OH radicals was determined in a slow-flow reactor with pulsed laser photolysis/laser-induced fluorescence technique. Temperatures ranged from 297 to 570 K at nominal pressures of 2, 5, and 10 bar (bath gas: helium). The very weak temperature dependence of the obtained rate coefficient can be expressed as: k1(T) = (2.9 ± 0.5) × 10−12 exp[(126 ± 61)/T] cm3 s−1. A significant pressure dependence was not observed. The results are in very good agreement with literature data for temperatures up to 370 K whereas differences occur at T > 400 K.

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