Add time:07/17/2019         Source:sciencedirect.com

Tert-butyl and tert-amyl ethers afford the corresponding tert-butyldimethylsilyl ethers when treated by one equivalent of tert-butyldimethylsilyl triflate (TBDMSOTf), followed by one equivalent of 2,6-lutidine. However, treatment by a catalytic amount of TBDMSOTf without base, led to the corresponding free alcohols.

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