Deprotonation of 2-(2-aminoethylamino)ethanol complexes of platinum(II, IV) and palladium(II) with liquid ammonia and potassium amide-Science-Chemical Encyclopedia-lookchem

Deprotonation of 2-(2-aminoethylamino)ethanol complexes of platinum(II, IV) and palladium(II) with liquid ammonia and potassium amide
Add time:08/24/2019 Source:sciencedirect.com

Toward liquid ammonia at −75°, hn complexes of Pt(II, IV) and Pd(II) exhibit the following types of behavior: (1) No reaction, (2) partial or complete ligand substitution, (3) deprotonation accompanied by ligand substitution and (4) partial ligand substitution followed by disproportionation. With potassium amide in ammonia, both deprotonation and ligand substitution reactions were observed although most of the cases studied led to inconclusive results.

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