Add time:07/17/2019 Source:sciencedirect.com
The asymmetric oxidative coupling reaction between 2-naphthol or binaphthol derivatives and 3-hydroxy-2-naphthoate derivatives with the copper(I)-(S)-(−)-isopropylidenebis(4-phenyl-2-oxazoline) catalyst was carried out. The reaction proceeded in a highly cross-coupling selective manner (≤99.7%) to produce the binaphthyl or quaternaphthyl derivative in good yield (≤92%) with enantioselectivity of up to 74%.
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