Add time:08/24/2019         Source:sciencedirect.com

Organopalladium halides, acetates, triflates and similar derivatives lacking β sp3-bonded hydrogens generally react easily with unhindered alkenes to form new alkenes in which an original, vinyl hydrogen is replaced by the organic group of the palladium reactant. The reactions occur in solution. Other Group VIII metals are ineffective in bringing about this transformation in acceptable yields. In the palladium reaction the organopalladium(II) reactant is reduced to the zero valent state while the halide, acetate, triflate or other, initial anionic ligand is converted into the corresponding acid (equation 1). If alkyl groups are attached directly to the double-bond carbons, double-bond rearrangement may occur and allylically substituted products can be produced. Normally, substitution occurs before any double-bond rearrangement occurs in the reactant alkene and the substituent is placed on one of the initial double-bond carbons (equation 2). Rearrangement of the double bond along a hydrocarbon chain to positions more distant from the substituent than the allylic position is occasionally observed, most often when X is a halogen and the halogen acid produced by the reaction is not neutralized as it is formed by inclusion of a base.

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