Experimental study and ERAS modeling of the excess molar enthalpy of (acetonitrile + 1-heptanol or 1-octanol) mixtures at (298.15, 313.15, and 323.15) K and atmospheric pressure-Science-Chemical Encyclopedia-lookchem

Experimental study and ERAS modeling of the excess molar enthalpy of (acetonitrile + 1-Heptanol (cas 111-70-6) or 1-octanol) mixtures at (298.15, 313.15, and 323.15) K and atmospheric pressure
Add time:08/23/2019 Source:sciencedirect.com

As a continuation of our studies on excess functions of binary systems, experimental data of excess molar enthalpy (HmE) of (acetonitrile + 1-heptanol or 1-octanol) mixtures have been determined as a function of composition at (298.15, 313.15, and 323.15) K at atmospheric pressure using a modified 1455 PARR mixture calorimeter. The HmE is positive for both systems over the whole composition range. The applicability of the ERAS-Model to correlate HmE of the mixtures studied was tested. The agreement between experimental and calculated values is satisfactory.

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