Add time:08/23/2019         Source:sciencedirect.com

Raman spectra of ethylene glycol dimethyl ether-d10 and Diethylene Glycol Dimethyl Ether (cas 111-96-6)-d14 were measured in the liquid and solid states, and spectral analysis was made on the basis of normal-coordinate treatment. The previous force field for the oxyethylene group was refined in the light of the newly obtained experimental data for these compounds together with those for the undeuterated oligo(oxyethylene) compounds. The present study has demonstrated the importance of the use of experimental data for the deuterated compounds in deriving the molecular force field from the vibrational wave-numbers.

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