Sequential claisen and cope rearrangement for formation of 3-(-1-methylethyl)-substituted α,β-unsaturated aldehydes-Science-Chemical Encyclopedia-lookchem

Sequential claisen and cope rearrangement for formation of 3-(-1-methylethyl)-substituted α,β-unsaturated aldehydes
Add time:08/22/2019 Source:sciencedirect.com

3-(1-Methylethyl)-7-methyl2,6-octadienal, was prepared from 1,1,3-triethoxy-3,4-dimethylpentane and 3-methyl-2-buten-l-ol in a one-pot procedure utilising Claisen and Cope rearrangement of an intermediate dienol-allyl ether.

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