Add time:08/21/2019         Source:sciencedirect.com

Preliminary studies on the biosynthesis of tolytoxin (1) in the terrestrial blue-green alga Scytonema mirabile BY-8-1 are reported. Incorporation experiments with [1,2-13C] acetate, [1-13C,18O]acetate, [1,2-13C]glycine, [2-13C,15N]glycine and [methyl- 13C]methionine indicate that the carbon chain of tolytoxin is a polyketide assembled from a glycine starter unit and 15 acetate units. The one-carbon branches on the polyketide chain originate from the tetrahydrofolate C1 pool.

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