Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-methoxypropene-Science-Chemical Encyclopedia-lookchem

Superbase-catalysed addition of methanol to propyne and allene: an expedient synthesis of 2-Methoxypropene (cas 116-11-0)
Add time:08/22/2019 Source:sciencedirect.com

In the superbase catalytic systems ButOK/NMP, AmtOCs/NMP and KOH/DMSO, methanol readily adds to propyne and allene at 100–120 °C and atmospheric pressure to afford 2-methoxypropene in 80–97% yield with 75–94% methanol conversion.

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