Add time:07/12/2019         Source:sciencedirect.com

Tensimetric and liquid ammonia extraction studies on the system VBr3NH3 show that the overall ammoniate VBr3.7NH3, formed at −36° is a mixture of VBr2NH2.5NH3 and NH4Br. The ammonobasic vanadium (III) bromide is soluble in liquid ammonia solutions of ammonium bromide so that VBr3 is largely soluble in ammonia. Reaction with alkali metal in ammonia solutions yields the inside M1V(NH)2 and the alkali metal amide. The thermal decomposition of the reaction products has been studied.

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