Add time:08/24/2019 Source:sciencedirect.com
Piperidinium hexathiocyanatochromate(III), (pipH)3[Cr(NCS)6], was synthesized using the molten salt pipHSCN and was found to contain nitrogen-bonded thiocyanate. The (pipH)3[Cr(NCS)6] decomposes in the range 250–370°C with the primary reaction being complete disruption of the compound to Cr(NCS)3(s) and pipHSCN(g). The reaction appears to be zero order with an activation energy of 82.4 ± 6.0 kJ mol−1. Decomposition of Cr(NCS)3 takes place at higher temperatures, but the reaction is somewhat variable.
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