Add time:07/13/2019 Source:sciencedirect.com
(1-Trimethylsilanylmethyl-vinyl)-phosphonic esters are synthesised via Wittig–Horner reactions starting from methylenediphosphonic esters. The reactions of (1-trimethylsilanylmethyl-vinyl)-phosphonic esters with NsONHCO2Et and CaO, produce α-methylene N-(ethoxycarbonyl) β-amino phosphonic esters, isolated up to 60% yield, through addition of (ethoxycarbonyl) amine function on the double bond and silyl group elimination.
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