Add time:08/25/2019         Source:sciencedirect.com

The synthesis of the protected TTF tetrathiolate 2,3,6,7-tetrakis(2-cyanoethylthio)tetrathiafulvalene (TCE-TTF), as well as those of five new radical cation salts [TCE-TTF](X), X− = PF6−, CF3SO3−, BF4−, obtained by electrocrystallization technique is presented. Five crystal structures of these materials based on their fully oxidized donor molecules are described. The flexibility of the cyanoethylene arm yields two conformations cis and trans to the molecule. Then compounds with PF6− and BF4− anions crystallized as two different phases. All these materials are insulators, and the magnetic studies of one phase of [TCE-TTF](PF6) revealed an antiferromagnetic behavior.

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