Controllable single- or double-oxa-Michael addition of ynones with alcohols: Synthesis of 3-alkoxyprop-2-en-1-ones and 3,3-dialkoxypropan-1-ones-Science-Chemical Encyclopedia-lookchem

Controllable single- or double-oxa-Michael addition of ynones with alcohols: Synthesis of 3-alkoxyprop-2-en-1-ones and 3,3-dialkoxypropan-1-ones
Add time:08/29/2019 Source:sciencedirect.com

Single- or double-oxa-Michael addition of ynones with various alcohols was achieved at room temperature. (E)-3-Alkoxyprop-2-en-1-ones and 3,3-dialkoxypropan-1-ones were efficiently synthesized by time-controlling approach. This protocol has advantages of wide range of substrates, no transition metal catalyst, mild condition, high yield and high stereoselectivity.

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