[(tert-Butyldimethylsilyl)oxy]methanethiol and [(tert-butyldiphenylsilyl)oxy]methanethiol—nucleophilic protected H2S equivalents-Science-Chemical Encyclopedia-lookchem

[(tert-Butyldimethylsilyl)oxy]methanethiol and [(tert-butyldiphenylsilyl)oxy]methanethiol—nucleophilic protected H2S equivalents
Add time:09/01/2019 Source:sciencedirect.com

[(tert-Butyldimethylsilyl)oxy]methanethiol [HSCH2OSiMe2Bu-t] is a nucleophilic reagent for introduction of a protected bivalent sulfur; this reagent is complementary to the electrophilic reagent p-MeC6H4SO2SCH2OSiMe2Bu-t. The thiol is prepared by the action of HSLi on tert-butyl(chloromethoxy)dimethylsilane [ClCH2OSiMe2Bu-t] and it reacts with alkyl bromides to give protected thiols.

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