Reactions of poly(methoxycarbonyl)-substituted cycloheptatrien-1-yl- and (N-mesylaminoethenyl)cyclopentadienyl anions with some aromatic cations-Science-Chemical Encyclopedia-lookchem

Reactions of poly(methoxycarbonyl)-substituted cycloheptatrien-1-yl- and (N-mesylaminoethenyl)cyclopentadienyl anions with some aromatic cations
Add time:08/27/2019 Source:sciencedirect.com

A new original route for the construction of cage structures containing seven electron-withdrawing groups in a molecule is reported. This method is based on the reaction of stable organic cations with a cycloheptatrienyl anion totally substituted with methoxycarbonyl groups. After the formation of a C–C bond between two different carbocycles, some further transformations take place to give cage structures. Reactions of the same cations with N-mesyl-Z-1-[1,2-bis(methoxycarbonyl)-2-(methoxycarbonylamino)ethen-1-yl]-2,3,4,5-tetrakis(methoxycarbonyl)cyclopentadienyl anion affording novel organic salts were also studied.

We also recommend Trading Suppliers and Manufacturers of [2-(Methoxycarbonyl)-2-propenyl]tributylstannane (cas 132841-83-9). Pls Click Website Link as below: cas 132841-83-9 suppliers

Prev:A series of new emissive mononuclear copper(I) bipyridyl complexes bearing the methoxycarbonyl groups
Next: Synthesis and structural characterization of bis[(4S,5R)-4-methoxycarbonyl-5-methyl-1,3-oxazolidine]copper(II) dichloride and bis[(4S,5R)-4-methoxycarbonyl-5-methyl-2-oxazoline]-[(4S,5R)-4-methoxycarbonyl-5-methyl-1,3-oxazolidine]ruthenium(III) trichloride)

Click to view details

Encyclopedia