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  • ArticleEfficient soluble deep blue electroluminescent dianthracenylphenylene emitters with CIE y (y ≤ 0.08) based on triplet-triplet annihilation
  • Add time:08/29/2019         Source:sciencedirect.com

    It has been challenging to develop deep blue organic molecular fluorescent emitters with CIE y (y ≤ 0.08) based on triplet-triplet annihilation (TTA). Here, we report facilely available dianthracenylphenylene-based emitters, which have a 3,5-di(4-t-butylphenyl)phenyl moiety at the one end and 4-cyanophenyl or 3-pyridyl at the other end, respectively. Both fluorophores show a high glass transition temperature of over 220 °C with a thermal decomposition temperature of over 430 °C at an initial weight loss of 1%. The preliminary characterizations of the organic light-emitting diodes (OLEDs) that utilized these nondoped emitters provided high EQEs of 4.6%−5.9% with CIE coordinates (0.15, 0.07–0.08). The analysis of the EL transient decay revealed that TTA contributed to the observed performance. The results show that the new emitters are attractive as a potential TTA-based host to afford stable deep blue fluorescent OLEDs.

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