Add time:08/26/2019         Source:sciencedirect.com

The electrophysical reaction of rubidium polytungstate Rb4W11O35 (RWO) on fast humidity impact has been investigated by studying the influence of wet air pulse of 1–3 s of duration on the peculiarities of dynamic current–voltage (I–V-) and charge-voltage (Q–V-) loops and transient current–time (I–t-) curves. The revealed peculiarities of hysteretic I–V- and Q–V-loops and I–t-curves for RWO subjected to humidity impact were compared with similar ones observed for water damaged hydrogen-bounded ferroelectric triglycine sulphate (TGS) crystals. The obtained data indicate at least two possible scenarios of polar reaction on the humidity impact, namely protonic/ionic space charge transfer and ferroelectric-like reversible polarization in surface RWO conglomerate disturbed by dipolar H2O adsorbate. Owing to a high surface activity the RWO can be considered as one of promising materials for creating humidity sensitive elements of environment monitoring systems. The direct humidity-to-frequency conversion was realized using LC resonance or RC-relaxation generating units.

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