Add time:08/31/2019         Source:sciencedirect.com

Reaction of metallic samarium firstly with 2 equivalents of azobenzene in THF with the aid of catalytic amount of iodine and then with 1 equivalent of sodium cyclopentadienide successively afforded the title complex [(THF)3Na(μ-η5:η5-C5H5)(η2-PhNHNPh)Sm]2(μ-η2:η3-N2Ph2)2 (1). It was found that two-electron reduction and hydride-addition of azobenzene cooperated in the reaction. The hydride-addition reaction happened in the absence of any hydride-reagents. It is the first ate samarium–azobenzene complex and also the first samarium complex containing two different kinds of reduced azobenzene species.

We also recommend Trading Suppliers and Manufacturers of SAMARIUM HYDRIDE (cas 13598-32-8). Pls Click Website Link as below: cas 13598-32-8 suppliers