Add time:08/30/2019         Source:sciencedirect.com

Synthesis, crystal structure, and properties of hydrides of palladium and its intermetallic compounds are being reviewed. Focus is on crystal structure, phase diagram, interplay between hydrogen content and electronic or magnetic properties, diffusion and lattice gas behavior of hydrogen for palladium hydrides, and on synthesis and crystal chemical interpretation of hydrogenation reactions for palladium-rich compounds. Hydrogen embrittlement, heterogeneous catalysis, and isotope effects are briefly discussed. For palladium-rich compounds MPd3 (M = Mg, In, Tl, Bi, Mn) hydrogen induced rearrangement between close-packed crystal structures and its crystallographic interpretation are discussed in detail.

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