Add time:08/31/2019         Source:sciencedirect.com

Stereoselective alternating copolymerization of carbon monoxide with various alkenes is reviewed. Using Pd(II) complexes of chiral ligands, completely alternating, isotactic, and enantioselective copolymerizations have been achieved from aliphatic 1-alkenes and from vinylarenes. Alternating copolymerization of carbon monoxide with other olefins are also described, such as functionalized ones, dienes, and allenes. Polymer conformation is mentioned briefly both in solid phase and in solution.

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