Studies in marine macrolide synthesis: Asymmetric synthesis of C1-C15/C16 subunits of swinholide A and scytophycin C.-Science-Chemical Encyclopedia-lookchem

Studies in marine macrolide synthesis: Asymmetric synthesis of C1-C15/C16 subunits of swinholide A and scytophycin C.
Add time:08/31/2019 Source:sciencedirect.com

The aldehyde 8, a C1-C15 subunit of swinholide A, was prepared in 10 steps (14.5% yield, 78% ds) by starting with the asymmetric aldol reaction, 15 + 17 → 18. Conversion into the corresponding ethyl ketone 9 provides a C1-C15 subunit of scytophycin C.

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