Add time:07/13/2019         Source:sciencedirect.com

The X-ray structures of two geometric isomers of 5-(2-chlorobenzylidene)-creatinine (1) are reported. In the crystal of almost planar 1-(E) hydrogen bonded centrosymmetric dimmers dominate, while in the structure of 1-(Z), adopting the twisted conformation, helical chains motifs, subsequently intertwined in braids, are preferred. Both creatinine analogs were found to crystallize in the 2-amino tautomeric form. X-ray investigations have been supported with 1H and 13C NMR data that confirmed 2-amino form also in DMSO solutions of (E)- and (Z)-5-(2-chlorobenzylidene)-creatinine.

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