The solution conformation of 1-(3,5-dimethylphenyl)methyl-3(S)-(1H-indol-3-yl)methyl-6(S)-phenylmethyl-2,5-piperazinedione (1): An NMR and molecular modelling study-Science-Chemical Encyclopedia-lookchem

The solution conformation of 1-(3,5-dimethylphenyl)methyl-3(S)-(1H-indol-3-yl)methyl-6(S)-phenylmethyl-2,5-piperazinedione (1): An NMR and molecular modelling study
Add time:08/29/2019 Source:sciencedirect.com

Comparison of NMR data with structures from molecular modelling of 1-(3,5-dimethylphenyl)methyl-3(S)-(1H-indol-3-yl)methyl-6-(S)-phenylmethyl-2,5-piperazinedione (1) showed it to have a specific solution conformation with the phenyl ring over the diketopiperazine ring and the tryptophan sidechain in the [G−o] rotamer.

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