Add time:09/04/2019         Source:sciencedirect.com

The fac-[Re(CO)3(2,2′-biquinoline)Cl] complex has been obtained in reaction of Re(CO)5Cl with 2,2′-biquinoline. The compound has been studied by IR, UV–Vis spectroscopy and X-ray crystallography. The molecular orbital diagram of the tricarbonyl has been calculated with the density functional theory (DFT) method. The spin-allowed singlet–singlet electronic transitions of [Re(CO)3(2,2′-biquinoline)Cl] have been calculated with the time-dependent DFT method, and the UV–Vis spectrum of the title compound has been discussed on this basis.

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