Add time:08/30/2019         Source:sciencedirect.com

Publisher SummarySince the metal alkoxidesM(OR), were first comprehensively reviewed in 1960, considerable progress has been maintained and the next major review in 1967 quoted over three hundred references. The most significant advances have involved the chemistry of the transition metal alkoxides with the emphasis on the ligand field aspects of the alkoxo group (e.g., electronic spectra, magnetism, etc.) and on X-ray crystallographic and NMR structural determinations. Industrial applications have been concerned with metal alkoxides as components of soluble Ziegler-Natta catalysts for olefin polymerization and also as sources for the production of pure metal oxides. The metal dialkylamides M(NR,) are of special interest, in that they contain covalent metal-nitrogen bonds, and occupy a position between the metal alkoxides and the metal alkyls. The field has not been fully reviewed, hitherto. However, excellent reviews have recently appeared on titanium dialkylamides and the reactivity of metal-dialkylamido bonds.

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