Add time:08/31/2019         Source:sciencedirect.com

Transition metal ion complexes of the potentially bidentate ligand 2-pyridylcarbinol N-oxide have been prepared. They are characterized and identified by chemical analysis and physical measurements. Their IR and electronic spectra are discussed with regard to monodentate or bidentate bonding of the ligand. The Cr(III) and Fe(III) complexes each contain two 2-pyridylcarbinol N-oxide ligands and a conjugate base of the carbinol in their coordination spheres. The remaining metal ions crystallized with either four (Mn(II), Ni(II), Cu(II), Zn(II)) or six (Co(II)) neutral ligands.

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