Synthesis, crystal structure and properties of manganese(II) hexafluoroacetylacetonates Mn(hfa)2(H2O)2 and KMn(hfa)3-Science-Chemical Encyclopedia-lookchem

Synthesis, crystal structure and properties of manganese(II) hexafluoroacetylacetonates Mn(hfa)2(H2O)2 and KMn(hfa)3
Add time:08/29/2019 Source:sciencedirect.com

Two manganese(II) hexafluoroacetylacetonate complexes, dihydrate, the Mn(hfa)2(H2O)2 (1), and the bimetallic KMn(hfa)3 (2) have been synthesized and characterized by X-ray single crystal structure analysis. They have a molecular structure and a polymeric structure, respectively. The high stability of 2 allowed sublimation without decomposition. It was then used as a precursor for MOCVD of fluoroperovskite, KMnF3.

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