Add time:08/29/2019         Source:sciencedirect.com

A series of novel derivatives of the 1,3-tropolone (β-tropolone) system—2-(2-quinolyl)-5,6,7-trichloro-1,3-tropolones and 2-(2-quinolyl)-4,5,6,7-tetrachloro-1,3-tropolones have been prepared by the acid-catalyzed reaction of 2-methylquinolines with 3,4,5,6-tetrachloro-1,2-benzoquinone. The molecular structures of two compounds, 2-(4-chloro-6,8-dimethyl-5-nitro-2-quinolyl)-5,6,7-trichloro-1,3-tropolone 8 and 2-(4-chloro-7,8-dimethyl-5-nitro-2-quinolyl)-4,5,6,7-tetrachloro-1,3-tropolone 9, have been determined using X-ray crystallography. According to the performed DFT B3LYP/6-311++G∗∗ calculations the tautomeric (OH) and (NH) forms of β-tropolones 8 and 9 are nearly energy equivalent, the latter being more stabilized in polar media. Photolysis of 2-(2-quinolyl)-1,3-tropolones in heptane solution leads to the disrotatory electrocyclic rearrangement resulting in the formation of a mixture of E- and Z-isomers of 3-[2(1H)-quinolinylyden]-bicyclo[3.2.0]hept-6-en-2,4-dione derivatives.

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