Add time:09/06/2019         Source:sciencedirect.com

An efficient route to prepare l-glucose and L-GALACTOSE (cas 15572-79-9) is described. The l-sugars are achieved by using the strategy of switching the functional groups at C1 and C5 of d-glucose and d-mannose. The oxidation and reduction of the silyl enol ether at C1 and the lead(IV) tetraacetate mediated oxidative decarboxylation at C5 are the key steps. l-Glucose and l-galactose are prepared in a convenient and inexpensive way.

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