Add time:09/03/2019 Source:sciencedirect.com
1,2:4,5-Di-O-isopropylidene-3-C-(5-phenyl-1,2,4-oxadiazol-3-yl)-β-d-psicopyranose 14 was synthesized stereoselectively from 1,2:4,5-di-O-isopropylidene-3-C-amidoximino-3-O-benzoyl-β-d-psicopyranose 8 using a novel procedure. Treatment of 8 with acetic anhydride, chloroacetyl chloride, propanic anhydride, or benzoyl chloride causes the 3-O-benzoyl group to undergo an intramolecular replacement reaction with neighboring group participation and transfer resulting in a more stable conjugation system of the 1,2,4-oxadiazol ring. A possible mechanism, as well as structural analysis and bioactivity are described.
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