Add time:09/01/2019         Source:sciencedirect.com

TEMPO (2,2,6,6-tetramethyl piperidine-1-oxyl) is electrochemically oxidized to a stable form of the cation (TEMPO+) in acetonitrile (CH3CN) or 1-butyl-3-methyl-imidazolium hexafluorophosphate ([BMIm][PF6]) media. Cyclic voltammograms were characterized by a well-defined one-electron reversible redox couple in both media at low scan rates. The reduced form of TEMPO+ is catalytically regenerated in a follow-up chemical reaction with benzyl alcohol (BA) in the presence of 2,6-lutidine. It was observed that in [BMIm][PF6], the redox currents are largely suppressed compared to that in CH3CN. The apparent heterogeneous electron-transfer rate constant (kapp0) of the quasi-reversible redox reaction of TEMPO was determined at a Pt electrode and found to be 1.9 × 10−3 cm s−1 and 4.5 × 10−2 cm s−1 in [BMIm][PF6] and CH3CN, respectively. With the aid of chronoamperometry (CA), the homogeneous rate constant for the catalytic oxidation of benzyl alcohol by TEMPO, in the presence of 2,6-lutidine in CH3CN was estimated to be 5.53 × 101 M−1 s−1 which is approximately double, relative to the value of 2.91 × 101 M−1 s−1 determined in [BMIm][PF6].

We also recommend Trading Suppliers and Manufacturers of 3-BENZYL-3-METHYL-PIPERIDINE (cas 136422-42-9). Pls Click Website Link as below: cas 136422-42-9 suppliers