1,6-Asymmetric induction in reactions between 6-hydroxy-5-methylhex-2-enyl(tributyl)stannane and aldehydes promoted by tin(IV) bromide-Science-Chemical Encyclopedia-lookchem

1,6-Asymmetric induction in reactions between 6-hydroxy-5-methylhex-2-enyl(tributyl)stannane and aldehydes promoted by tin(IV) bromide
Add time:09/02/2019 Source:sciencedirect.com

(R)-6-Hydroxy-5-methylhex-2-enyl(tributyl)stannane 4 transmetallates on treatment with tin(IV) bromide to give an intermediate allyltin tribromide which reacts with aldehydes to give 1-substituted (Z)-6-methylhept-2-ene-1,7-diols 7 with excellent anti-1,6-asymmetric induction.

We also recommend Trading Suppliers and Manufacturers of 2-METHOXY-2-METHYLPROPYL BROMIDE (cas 19752-21-7). Pls Click Website Link as below: cas 19752-21-7 suppliers

Prev:Research ArticlesCactus Alkaloids IV. Macromerine (cas 19751-75-8) from Coryphantha runyonii
Next: An expeditious synthesis of tamoxifen, a representative SERM (selective estrogen receptor modulator), via the three-component coupling reaction among aromatic aldehyde, Cinnamyltrimethylsilane (cas 19752-23-9), and β-chlorophenetole)

Click to view details

Encyclopedia