Add time:09/08/2019         Source:sciencedirect.com

The appearance of the bands in the O-H and O-D stretching region of the spectra of the title compound and in that of its slightly deuterated analogue indicates a larger spread of the H-bond strengths in the structure of this compound than in that of its cobalt analogue. The numerical values of the OW⋯distances are not appropriate indicators for the hydrogen-bond strengths. The bands due to water librations were located on the basis of their temperature sensitivity and shift on deuteration.

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