Add time:09/24/2019         Source:sciencedirect.com

Laser-ablated ruthenium or osmium atom reactions with CO and NO mixtures in solid argon produce unsaturated metal carbonyl nitrosyls including M(CO)(NO) and 18-electron configuration M(CO)2(NO)2 molecules (M = Ru, Os). The observed absorption bands of reaction products are identified by isotopic substitution, isotopic ratios and isotopic distributions (13CO, 15NO, and mixtures). DFT (B3LYP and BP86) vibrational fundamental calculations reproduce observed frequencies and isotopic shifts very well. The bonding and reaction mechanism are discussed.

We also recommend Trading Suppliers and Manufacturers of OSMIUM CARBONYL (cas 15696-40-9). Pls Click Website Link as below: cas 15696-40-9 suppliers