Add time:07/23/2019         Source:sciencedirect.com

Ion–ion and ion–solvent interactions for N,N/-ethylene-bis(salicylideneiminato)-diaquochromium(III) chloride, [Cr(salen)(H2O)2]Cl, dissolved in solutions of 1-butyl-2,3-dimethylimidazolium tetrafluoroborate, [bdmim]BF4 (0.005 to 0.020 mol · dm−3) in methanol (MeOH) were investigated by a combination of physicochemical properties at 298.15, 308.15 and 318.15 K under ambient pressure. From measured solution densities and viscosities apparent molar volume (φV), the slope (SV∗), standard partial molar volume (φV0), transfer volume (ΔtφV0), the viscosity B-coefficient, its temperature derivative (∂B/∂T), solvation number (Sn), etc. were calculated and discussed on the basis of ion–ion and ion–solvent interactions. In the investigated temperature range, the relation: φV0=a0+a1T, was used to determine the temperature dependence of the partial molar volumes φV0, i.e., partial molar expansibilities (φE0). Temperature dependence of the viscosity B-coefficient (∂B/∂T) values revealed the complex to be a long-range structure breaker. Thermodynamics of viscous flow were discussed on the basis of the transition state theory.

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