Add time:09/06/2019 Source:sciencedirect.com
The speciation of protic ionic liquids (ILs) has attracted high attention in the recent years, due to its effect in the properties of the resulting liquids. In this work we analyze the behavior of mixtures between triethylamine (N222) and acetic acid (HOAc), a system that generates controversy about its speciation. Using different synthetic strategies, liquids were obtained with molar compositions that were always between 1:2 and 1:4 mol/mol N222:HOAc. However, the experimentally observed normal boiling points indicate that the actual IL has a molar composition of 1:4 N222:[HOAc]/[OAc]−. Furthermore, when the synthesized liquid is mixed with the aprotic IL 1‑ethyl‑3‑methylimidazolium acetate, more triethylamine is expelled, indicating that the excess N222 forms an [HN222]+‑N222 complex rather than becoming ionized by the remaining HOAc present in the system. Our experimental data emphasizes the consideration of these systems not as mere “mixtures of ions and non-ionized molecules,” but as complex systems of oligomeric ions, with distinctive and characteristic properties.
We also recommend Trading Suppliers and Manufacturers of TRIETHYLAMMONIUM FORMATE (cas 15715-58-9). Pls Click Website Link as below: cas 15715-58-9 suppliers
About|Contact|Cas|Product Name|Molecular|Country|Encyclopedia
Message|New Cas|MSDS|Service|Advertisement|CAS DataBase|Article Data|Manufacturers | Chemical Catalog
©2008 LookChem.com,License: ICP
NO.:Zhejiang16009103
complaints:service@lookchem.com Desktop View