Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one-Science-Chemical Encyclopedia-lookchem

Enantiospecific total synthesis of 15-hydroxy-5-(methoxymethoxy)crinipellin-9-one
Add time:09/10/2019 Source:sciencedirect.com

Enantiospecific total synthesis of the crinipellin mentioned in the title was accomplished. In the present synthesis cyclopentane ring in campholenaldehyde was identified as the B-ring, two intramolecular rhodium carbenoid CH insertion reactions were employed for the construction of the A and C rings, and an intramolecular Michael addition reaction was utilized for the construction of the D-ring of crinipellin.

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